Adsorption from Solution - download pdf or read online

By R Ottewill (Eds.)

ISBN-10: 0125309805

ISBN-13: 9780125309806

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1 5 was obtained from equation ( 1 3 ) using the difference in surface tension between the two pure components. The best fit between model and experiment is obtained with t = O . 5 8 . The experimental surface tension of mixtures of cyclohexane (A) and benzene (B) at the temperature of 2 9 8 . 1 5 K, as reported by Lam and Benson (h), are shown in Fig. 3 . The solution thermodynamic data of Scatchard et al. ( 5 ) was used to compute the model surface tension. Qk x 1 0 m /mol, while K = 1 . 3 2 .

1982). D. Thesis, Bristol. 41. W. (1979). D. Thesis, Bristol. 42. H. (1975). , 14, 267. 43. Robert, L. (1963). , 256, 655; (1967). Bull. S. R. (1969). H. H. (1969). H. J. (1969). Thermo­ dynamics, l_, 573. 44. E. D. Thesis, Bristol. 45. V. E. (1975). Faraday Disc. Soc, 59_, 97. 46. D. W. (1981). , 7_9, 518. 47. G. (1970). H. (1971). , 35, 249; (1972). S. Faraday I, 68, 1799; (1973). 69, 1069. 48. Groszek, A. (1970). Soc, A314, 473. 49. , unpublished. 50. , unpublished. 51. Maher, P. (1983). D.

And Shinoda, K. (1975). Bull. Soc , Japan, _48, 324. , (1972). Soc, Faraday II, 68, 1439. E. Lane Department of Physical Chemistry University of Melbourne ParkviVie* Victoria* Australia* 3052. 1. INTRODUCTION Everett and his co-workers have made a number of important contributions to the study of surface activity coefficients. They have concentrated on relating surface activity coefficients with adsorption at the solid/solution interface. It is the intent of this contribution to consolidate these achievements, and to complement them with an examination of the relationship between the surface activity coefficients and the surface tension.

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Adsorption from Solution by R Ottewill (Eds.)


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